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Research

Keywords

状態図、熱分析、拡散

researchPicture

この図はNi-Co-Al-Ti四元系合金の相境界組成を一つの試料から1000組近く得た例である。2相領域内で幅広い組成分布を持つ試料に対し、微小領域の2相組織の母相及び析出相の組成を抽出する手法を適用し、従来法の160倍程度の高効率でのデータ取得に成功した。

Society memberships

日本金属学会, 日本ガスタービン学会

Research Center for Structural Materials
Title

Development of High-Throughput Measurement Techniques Using Heat-Treated, Composition-Graded Bulk Samples

Keywords

Ni-based superalloys, high-throughput measurement, phase diagram, diffusion

Overview

Commercial alloys are composed of many elements. To develop these alloys and understand their properties, we are developing high-throughput methods to efficiently obtain phase diagrams and property maps for multi-component alloys. The three fundamental elements of this method are as follows. ① By introducing gradients in composition and heat treatment temperature within a single test specimen, we create and use an aggregate of microspecimens with varying compositions and heat treatment temperatures. ② Properties are measured in each micro-region. (This includes the development of measurement methods.) ③ During measurement, we apply the automated measurement and analysis system we have developed. Employing our newly developed high-throughput method, we succeeded in comprehensively acquiring big data at an incredible efficiency—more than 100 times that of conventional methods.

Novelty and originality

● 各種微小領域試験に適したデザインの組成傾斜試料の作製 ● 擬四元ハイスループット実験状態図作製技術の開発 ● 温度傾斜熱処理試験を利用したハイスループット熱処理プロセス最適化手法の開発

Details

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The right figure shows an example in which nearly 1,000 sets of phase boundary compositions for a Ni-Co-Al-Ti quaternary alloy were obtained from a single sample. Constructing a multi-component phase diagram requires a large amount of phase boundary composition data, and using conventional methods is too time-consuming. In this experiment, we applied a method to extract the compositions of the matrix phase and the precipitate phase in a microstructure within a two-phase region from a sample with a wide composition distribution. We succeeded in acquiring data with a efficiency approximately 160 times higher than that of conventional methods.
The left figure summarizes an experiment in which a single-crystal sample of a Ni-based superalloy exhibiting dendritic segregation was heat-treated under a temperature gradient, and its microstructure was observed. The heat treatment equipment was developed in-house. The collected data provide a comprehensive understanding of the correlation between the microstructure and temperature and composition, serving as a guideline for optimizing heat treatment conditions for components. The time required to acquire the dataset of 4,500 data points—including sample preparation—was approximately two weeks, which is an extremely short period.
image

Summary

● バルクで用いられる材料のハイスループット特性評価試験に適した組成傾斜試料の作製手法を開発 ● 一つの試料で数十~数千組成の特性データを得ることにより、多元合金の組成-特性データベースを迅速に構築 ● Ni基超合金の組成・熱処理プロセスを極めて高効率に最適化
この機能は所内限定です。
この機能は所内限定です。

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