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研究内容

Keywords

bulk single crystals,epitaxy, optoelectronic devices

所属学会

日本結晶成長学会, 応用物理学会

電子・光機能材料研究センター
タイトル

novel functional optical crystals

キーワード

single crystal, crystal growth, scintillators, Faraday rotators, phosphors, piezoelectrics, semiconductors

概要

• Optical isolators are needed for laser machinery, marking, and high-power LDs. New novel Faraday rotators are demanded for higher laser powers and shorter wavelengths.
• Environmentally friendly, high-energy X-ray and compact, high-performance neutron scintillator single crystals are needed to realize a safe and secure society.

新規性・独創性

• Improvement of Tb-garnets for IR Faraday rotators and development of new UV-visible Faraday rotators.
• Materials with high light yield, stable without deliquescence, and capable of large single-crystal growth. Furthermore, development of materials possessing the specific properties required for X-ray and neutron applications.
• Development of novel crystal growth techniques, such as bulk single-crystal growth by hydrothermal synthesis

内容

• (Top) 2-inch diameter Tb₃(Sc,Lu)₂Al₃O₁₂ (TSLAG) single crystal. As a Faraday rotator for laser processing machines, it excels in quality, cost, and performance.
• (Lower left) CeF₃ single crystal Faraday rotator, useful from near-ultraviolet to visible wavelengths.
• (Lower right) CeF₃, PrF₃, and LiREF₄ (RE = Tb, Dy, Ho, Er, Yb) single crystals. Useful as Faraday rotators and laser crystals, covering deep ultraviolet to visible wavelengths.

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• (Top) Tb:YTaO₄ (YTO) single crystal grown by the FZ method. Useful as an X-ray scintillator. It is high density, exhibits higher light yield than CdWO₄ single crystals, and is Cd-free, making it environmentally friendly.
• (Lower left) Ce:Li₆Y(BO₃)₃ single crystal, useful as a neutron scintillator. It surpasses Li glass in Li concentration, luminescence, lifetime, and productivity.
• (Lower right) Ce:Lu₁.₈Y₀.₂SiO₅ (LYSO) single crystal grown by hydrothermal synthesis. Compared to crystals grown by the Czochralski method, it features lower defect levels and exclusive Ce³⁺ valency, which is expected to enhance luminescence.

まとめ

• Tb-Sc-garnets are already incorporated into Yb-amplified fiber-lasers by Fujikura Ltd.
• CeF₃ is implemented in commercial UV-VIS optical isolators.
• To realize a safe and secure society, we will accelerate the development of scintillator single crystals, aiming for larger size and higher quality.
• Advancement of single-crystal growth technology by the hydrothermal technique.

この機能は所内限定です。
この機能は所内限定です。

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