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低温工学・超電導学会

Research Center for Energy and Environmental Materials (GREEN)
Title

Development of a high-efficiency hydrogen liquefier/refrigerator

Keywords

Magnetic refrigeration, liquid hydrogen, cryogenics

Overview

LLiquid hydrogen is attracting attention as one of the candidate new energy carriers in a society aiming for carbon neutrality, and it is expected to play a new role and offer new possibilities in distributed power generation systems using renewable energy, as well as in mobility applications (buses, trucks, railways, ships, aircraft, and so on). While liquid hydrogen is a promising carrier from the standpoint of energy density, liquefaction requires cooling it to an extremely low temperature of 20 K (-253°C) at 1 atmosphere. In addition, during transport and storage, gas continuously evaporates due to natural heat ingress from the surroundings. In this research, we are developing and improving the efficiency of hydrogen liquefiers and of re-condensers, which reliquefy the evaporated gas (boil-off gas) and return it to the storage tank.

Novelty and originality

● Compared to conventional gas-cycle refrigerators that use gas compression and expansion, magnetic refrigerators have a higher theoretical liquefaction efficiency.
● Since it does not require a compressor, which is necessary for gas-cycle refrigerators, it enables a smaller size, lower power consumption, and quieter operation.
● By using a magnetic material optimized for the hydrogen liquefaction temperature (~20 K), the magnetocaloric effect can be maximized.
● With a new method called Active Magnetic Refrigeration (AMR), it is possible to expand the operating temperature range, which had previously been considered a weakness of magnetic refrigeration.

Details

image

In AMR, granular magnetic working material is packed into a container, and heat exchange gas is made to flow through the gaps between the particles in synchronization with the application of the magnetic field, thereby transporting the heat/cold generated in the magnetic working material. In the opposed-arrangement type AMR, the magnetic working material is located in two places, and a single magnet that generates the magnetic field moves back and forth. In the four-fold opposed-arrangement rotary AMR developed at NIMS, the magnetic working material is arranged in eight equal segments, and the magnetic field is varied by rotating four magnets.
This research aims to develop a magnetic refrigeration system that is more efficient than conventional systems. The figure above shows an example of a magnetic refrigerator built for hydrogen re-condensation; we are using this device to study how to improve the efficiency of hydrogen re-condensation through magnetic refrigeration. By changing the magnetic working material and the magnet material, the system can be adapted to a wide range of temperature ranges, giving it broad applicability.

Summary

[Achievements to Date] We succeeded in developing and demonstrating the principle of a refrigerator for hydrogen re-condensation that combines permanent magnets with a four-fold opposed-arrangement rotary AMR.
[Future Challenges] Further improvement in efficiency is desirable. Key challenges include optimizing the thermal design, including the heat exchangers, increasing the magnetic field strength of the magnets, and increasing the capacity of the magnetic working material.
[Path to Practical Application] We aim to conduct element-level tests of each component and, by integrating them, achieve a proof of concept toward practical application.

この機能は所内限定です。
この機能は所内限定です。

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