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Research

Keywords

High temperature deformation, Transparency, High Strength, Spark Plasma Sinting (SPS)

(1) High-Strain Rate Superplastic Ceramics (Figure: Top) We have discovered for the first time that even in highly rigid and brittle materials like ceramics, local plastic relaxation due to dislocation activity within grains plays an important role as a relaxation mechanism for superplastic deformation, similar to that in metallic alloys. By optimizing microstructures, we have realized high-strain rate superplastic ceramics (Patent No. 3837516) that can be processed with excellent strength comparable to metals even at deformation speeds 100 to 1000 times faster than conventional materials. (2) High-Strength, Broadband-Transparent Composite Ceramics (Figure: Middle) By optimizing the fine grain and composite structure through pulsed current sintering, we achieved high-strength, broadband-transparent ceramics that combine excellent light transmission and mechanical properties. Furthermore, we fabricated composite ceramics by laminating textured alumina on a spinel surface, achieving not only excellent broadband (400 nm-6 μm) in-line transmittance but also a 2.0-2.5 times improvement in mechanical properties compared to conventional materials (Patent No. 2023166658).

researchPicture

(3) Extending the life time of ceramics by healing cracks damage under a strong electric field (Figure: lower)
We have discovered a new healing technology (Patent No. 2022161388) that allows for the rapid healing of cracks and other damage of ceramics by applying a strong electric field treatment. This not only recovery the strength to its initial state after the healing treatment, but also enables the recovery (rejuvenation) of the material, thereby extending its life time of the ceramics. Recycle and reuse of ceramic components are difficult, and even if possible, they consume a lot of energy. This healing technology aims to reuse the components through repair, rather than discarding the used ceramic components and manufacturing new ones. If reuse becomes possible, it is expected to contribute to achieving carbon neutrality, which is a social issue, and realizing a material recycling society with 3Rs (Recycle, Reuse, Reduce).

PublicationsNIMS affiliated publications since 2004.

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Society memberships

日本金属学会, 日本セラミックス協会, 粉体粉末冶金協会

Research Center for Electronic and Optical Materials
Title

Development of complex polycrystalline optical ceramics and its bulk processing

Keywords

Polycrystalline optical ceramics, complex optical materials, high-entropy ceramics, bulking processes, external field effects, phosphors, light sources

Overview

Optical ceramics are important key components for sensor window and high-brightness light source optical materials for realizing a highly efficient, safe, and secure society. To achieve a breakthrough for realizing next-generation optical functional materials that satisfy those requirements, the challenging approach for developing new materials would be essential. Therefore, in addition to conventional simple component system, we are now conducting research on the development of new complex composite optical materials called as "medium-entropy" and "high-entropy" systems, as a challenging area that will realize breakthroughs in the field of optical ceramics. We are challenging ourselves with the synthesis of functional powders and the development of processes for creating polycrystalline optical devices from powders. This research is aiming to achieve from the synthesis of functional powders to the development of bulk processing of polycrystalline optical devices from the functional powders.
In particular, in order to realizing sensing applications, our research focus on the synthesis of complex compositional fluorescence powders, polycrystalline optical materials that possess broadband emission and transmittance from the visible to near-infrared (>1000 nm) range, as well as the development of its bulking processes for those functional powders.

Novelty and originality

Broadband traneparent materials from visible to near-infrared region
Development of complex polycrystalline optical materials
Development of a new bulk processing for realizing transparent polycrustalline ceramics
Optical materials that simultaneously posess optical and structural properties
Infrared phosphors and its bulk processing

Details

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For industrial applications as optical window materials and sensors, excellent mechanical and thermal properties are essential in addition to optical properties. However, it is not easy to realize multiple functional optical materials by simple component system, and hence, composite materials (CMC: Ceramic Matrix Composite) by combining several materials with different functional properties would be necessary. For example, the left figure shows a layered optical CMC ceramic with high strength and broadband transmission properties, which a high-hardness α-Al2O3 alumina phase was layered on the surface of the infrared transparent MgAl2O4 spinel. This material achieveded excellent broadband transmission properties while superimposing mechanical properties (high hardness) of 2.0 to 2.5 times greater than conventional materials. The realization of this multilayer optical material was achieved by optimizing the synthesis process and achieving a good bonding interface.

In the field of optoceramics, development of new material systems that achieve breakthroughs in the optical ceramics for opening new research areas. Recently, high-entropy ceramics that are fromed by mixing of the elements more than 5 elements has attracted attention. The researches of the high-entropy have firstly been conducted mainly in metallic materials, and new excellent functional properties have been reported. However, in recent years, the optical ceramics has also been confirmed in high-entropy ceramics. We have also succeeded to attain high-entropy broadband transparent polycrystalline ceramics, that posess laser oscillation and fluorescence by using homemade homogeneous and fine high-entropy powders.

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Summary

Polycrystalline optical ceramics, that can fabricate from powder materials using sintering techniques, can realize low cost, productivity, and large size, net shaping into the final form, as well as excellent mechanical properties. Furthermore, flexible microstructure design, including composition control, compounding with different phase, and refining the microstructure, enable to improve the properties enough for industrial applications.

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