SAMURAI - NIMS Researchers Database

NIMS Award Symposium 2026

HOME > Profile > KOBAYASHI, Yuka

Research Center for Macromolecules and Biomaterials
Title

Development of High-Performance Organic Electronic Materials and Inkjet Fine-Patterning Technology

Keywords

Functional organic materials, High-mobility organic materials, Organic thermoelectric materials, Inkjet fine patterning, Aqueous conductive ink

Overview

Organic electronics are expected to make broad contributions to the next-generation IT society. Currently, precise control of intermolecular interactions through molecular design and crystal engineering is making it possible to manipulate electronic properties. To date, based on a proprietary principle of introducing proton faults for charge control (without the need for dopants), we have successfully created various highly functional organic electronic materials with exceptional chemical stability. Furthermore, by utilizing aqueous conductive inks compatible with organic and biological materials, we have developed a fine-wiring technology completely free of high-boiling-point solvents, thereby expanding the potential of next-generation organic electronics from multiple perspectives.

Novelty and originality

● Rational design of dopant-free (air-stable), highly conductive organic materials ● On-demand design of electronic functions tailored to specific needs ● Morphology control through advanced molecular design ● Design of high-mobility organic materials via π-orbital engineering ● Development of inkjet fine-patterning technology utilizing room-temperature drying and high-boiling-point-solvent-free aqueous conductive inks

Details

Stable organic molecules with a closed-shell structure are inherently insulators. Conventionally, generating charge carriers required "mixing (doping)" multiple molecules to facilitate charge transfer. In contrast, by employing a molecular design that introduces proton faults alongside the delocalization of π-orbitals, open-shell molecules with an unpaired electron (zwitterionic radicals) can acquire chemically stable carriers without doping. This unique molecular design guideline has enabled the versatile creation of materials ranging from chemically stable organic semiconductors to organic metals.
The developed molecule, "tetrathiafulvalene-extended dicarboxylate (TED)," is the first single-component organic molecule to exhibit metallic conductivity under ambient pressure. The in-plane electrical conductivity of its layered single crystal exceeds 2300 S/cm at room temperature, ranking among the highest for organic materials. Moreover, it maintains this high conductivity even after several months of exposure to air, making it highly promising for various applications, including transparent electrodes. For the industrial application of these functional organic electronic materials, conventional patterning methods such as lithography are not always optimal. Therefore, we developed a next-generation fine-wiring technology that is fully compatible with biological and organic devices, eliminating the need for high-boiling-point solvents or thermal processing during the wiring process.

Summary

Chemical stability is a critical factor for the practical application of organic electronic materials. We have demonstrated that dopant-free organic electronic materials, based on our original molecular design , can maintain high electronic functionality over long periods in the atmosphere, proving this to be an exceptionally effective design guideline. Furthermore, by developing a novel fine-patterning technology rather than relying on existing techniques optimized for inorganic materials, we have unlocked the potential to develop novel devices that fully leverage the high functionality of biological and organic materials—an achievement previously considered difficult.
この機能は所内限定です。
この機能は所内限定です。

▲ Go to the top of this page