- Address
- 305-0047 1-2-1 Sengen Tsukuba Ibaraki JAPAN [Access]
External affiliations
- 2025.12-2026.12 Guest Researcher, Max Planck Institute for Sustainable Materials
Research
- Keywords
腐食防食,コンクリート,水素侵入,医療用金属材料
PublicationsNIMS affiliated publications since 2004.
Research papers
- Kotaro Doi, Sachiko Hiromoto. Synergistic Effects of Plastic Deformation and Chloride Ions on Corrosion Initiation of Steel Rebars in Simulated Concrete Pore Solution. Journal of The Electrochemical Society. 169 [8] (2022) 081505 10.1149/1945-7111/ac87d3
- Kotaro Doi, Sachiko Hiromoto, Tadashi Shinohara, Koichi Tsuchiya, Hideki Katayama, Eiji Akiyama. Role of mill scale on corrosion behavior of steel rebars in mortar. Corrosion Science. (2020) 108995 10.1016/j.corsci.2020.108995
- Kotaro Doi, Sachiko Hiromoto, Hideki Katayama, Eiji Akiyama. Effects of Oxygen Pressure and Chloride Ion Concentration on Corrosion of Iron in Mortar Exposed to Pressurized Humid Oxygen Gas. Journal of The Electrochemical Society. 165 [9] (2018) C582-C589 10.1149/2.1421809jes
Books
- 土井 康太郎, 西田 孝弘, 佐伯 竜彦, 高橋 駿人, 上田 隆雄, 染谷 望, 齊藤 亮介, 高谷 哲. 6. コンクリート中の鋼材腐食を律速する酸素と水分状態. コンクリート技術シリーズ 131 コンクリート中への水分浸透評価とその活用に関する研究小委員会(362 委員会)成果報告書. 土木学会, 2022, 6.
- 染谷 望, 土井 康太郎, 西田 孝弘, 上田 隆雄, 斎藤 豪. 8. コンクリート中の鋼材の分極抵抗を用いた腐食速度評価. コンクリート技術シリーズ 131 コンクリート中への水分浸透評価とその活用に関する研究小委員会(362 委員会)成果報告書. 土木学会, 2022, 4.
Proceedings
- 左藤眞市, 土井 康太郎, 高谷哲. コンクリート中の酸素還元反応の特徴. コンクリート工学年次論文集. 46 [1] (2024) 781-786
- 土谷 浩一, 姜 保真, 土井 康太郎, 廣本 祥子, チャン ジェン. 異形鉄筋ミル・スケールの微細組織と腐食への影響. コンクリート構造物の補修,補強,アップグレード論文報告集. (2019) 187-192
- 土井 康太郎, 廣本 祥子, 秋山英二. 電気化学的不働態皮膜破壊と加圧酸素ガス供給によるモルタル埋設鉄の加速腐食. コンクリート構造物の補修, 補強, アップグレード論文報告集. (2018) 1016-1-1016-6
Presentations
- 土井 康太郎, 福田 涼介, 羽富 圭祐, 廣本 祥子. 非鉄金属材料の水素侵入・水素脆化に関与する材料表面性状. 日本金属学会第5分野オンライン講演会. 2024 Invited
- 土井 康太郎. 高酸素反応促進技術によるインフラ構造材料の腐食機構解明と耐食性向上. 第74回スガウェザリング学術講演会. 2023 Invited
- DOI, Kotaro, HIROMOTO, Sachiko. Hydrogen Permeation in Magnesium Alloys at Room Temperature. EuroCorr2024. 2024
Misc
- 土井 康太郎. はばたく 腐食研究の道に進んで. まてりあ. 56 [4] (2017) 302 10.2320/materia.56.302
- 土井 康太郎, 廣本 祥子, 秋山英二. 加圧酸素ガス供給によるモルタル埋設鉄筋の腐食加速. 第65回材料と環境討論会講演集. (2018) A-101-1-A-101-2
- 土井 康太郎, 寺西 亮, 轟 直人, 小畠 淳平, 齊藤 信雄, 宮部 さやか, 小嶋 隆幸. 企画にあたって. まてりあ. 61 [7] (2022) 391-392 10.2320/materia.61.391
Published patent applications
Society memberships
日本金属学会, 腐食防食学会, 土木学会, 日本鉄鋼協会, 日本ばね学会, 表面技術協会, 軽金属学会
Awards
- NIMS理事長賞 研究奨励賞 (2025)
- SATテクノロジー・ショーケース2025 インフラ×異分野 イノベーション賞 最優秀賞 (2025)
- 令和6年度 科学技術分野の文部科学大臣表彰 若手科学者賞 (2024)
- スガウェザリング技術振興財団 科学技術奨励賞 (2023)
- 腐食防食学会 進歩賞 (2023)
- NIMS理事長賞 進歩賞 (2020)
- 日本金属学会 奨励賞 (2019)
- 日本ばね学会 論文賞 (2017)
Funds
- 公益信託ENEOS水素基金 (2025)
- 軽金属奨学会 研究補助金 (2025)
- 令和5年度アルミニウム研究助成事業 7000系Al合金の不働態皮膜の力学的損傷に伴う腐食と水素侵入 (2023)
- 軽金属奨学会 研究補助金 (2022)
- 科研費 基盤研究(C) (2021)
- スガウェザリング技術振興財団 研究助成 (2021)
- 科研費 若手研究 (2019)
- 卓越研究員事業 (2018)
- 科研費 若手研究(B) (2017)
Research Center for Structural Materials
Elucidation of Corrosion Degradation Mechanisms and Development of Corrosion Protection Strategies for Metallic Materials in Infrastructure
Corrosion, Corrosion Protection, Metallic Materials, Corrosion-Resistant Steels, Concrete, Oxygen Reduction, Surface Treatment, Hydrogen Entry
Overview
I conduct research on corrosion and corrosion protection with the aim of improving the long-term reliability of metallic materials used in social infrastructure. In particular, I study the corrosion of steel in reinforced concrete, focusing on the effects of oxygen reduction, chloride ions, pH, oxide films, and corrosion products through electrochemical analysis. I have also developed a unique accelerated evaluation technique using high-pressure oxygen, which is applied to the elucidation of corrosion mechanisms and the rapid assessment of corrosion-resistant steels and surface-treated materials. In addition, I am working on the performance evaluation and practical implementation of a novel corrosion-resistant reinforcing steel developed at NIMS. My research also covers hydrogen ingress and hydrogen embrittlement in high-strength steels, aluminum alloys, and magnesium alloys under corrosive environments, with the ultimate goal of developing effective corrosion protection strategies for metallic materials used in infrastructure and transportation systems.
Novelty and originality
● Electrochemical studies of corrosion and corrosion protection of steels and non-ferrous metals
● Rapid corrosion evaluation of reinforcing steel in concrete, reproducing degradation that takes decades under actual environments
● Development and practical implementation of NIMS-developed corrosion-resistant reinforcing steel
● Accelerated formation of corrosion-resistant surfaces with more than 10 times the corrosion resistance of bare zinc
● Electrochemical hydrogen permeation testing using organic solvents
● Elucidation of the effects of oxide films on corrosion initiation and hydrogen ingress
Details
I conduct research on the corrosion and corrosion protection of steels and non-ferrous metals, with the aim of improving the long-term reliability of metallic materials used in social infrastructure. In particular, I study the corrosion of reinforcing steel in concrete using electrochemical techniques, focusing on how factors such as oxygen reduction, chloride ions, pH, oxide films, and corrosion products influence corrosion behavior.
One of the core technologies in my research is a unique high-oxygen reaction acceleration technique. In this method, metal specimens or mortar specimens containing embedded steel are placed in a pressure-resistant gas chamber and exposed to high-pressure oxygen. This increases the dissolved oxygen concentration near the metal surface and accelerates the oxygen reduction reaction, which often controls the overall corrosion rate. As a result, corrosion phenomena that would normally require months or years under conventional conditions can be reproduced within days to weeks. Using this technique, I have quantitatively evaluated the effects of concrete cover thickness, moisture conditions, chloride ions, pH, and oxide films on the corrosion of reinforcing steel. I have also shown that defects in the mill scale formed on reinforcing steel can act as initiation sites for corrosion.
This high-oxygen reaction acceleration technique is also being extended to the evaluation and development of corrosion-resistant materials and surface treatments. I am conducting performance evaluations of a novel corrosion-resistant reinforcing steel developed at NIMS, including comparisons with conventional steels and analyses of its corrosion mechanisms, with the aim of practical implementation. In addition, by taking advantage of the fact that the formation of protective films can be controlled by oxygen reduction, I am developing an accelerated process for producing corrosion-resistant zinc surfaces that exhibit more than ten times the corrosion resistance of bare zinc.
In addition to these studies, I investigate hydrogen ingress and hydrogen embrittlement in high-strength steels, aluminum alloys, and magnesium alloys. My research includes analyses of hydrogen entry associated with corrosion and wear, as well as the development of an electrochemical hydrogen permeation method using organic solvents that can be applied to highly corrosion-prone light metals. Through these approaches, I aim to clarify how oxide films and surface conditions affect hydrogen ingress and embrittlement behavior.
Summary
My research has combined fundamental studies of electrochemical reactions, surface films, and hydrogen ingress with the evaluation and practical application of corrosion-resistant materials and surface treatments. Looking ahead, I aim to move beyond the evaluation of individual corrosion phenomena and develop a more unified understanding of the interactions among materials, environments, and surface conditions, ultimately establishing methodologies capable of predicting corrosion initiation and progression.
I also seek to connect accelerated testing with degradation behavior under actual service conditions, thereby contributing to longer material lifetimes and more advanced maintenance strategies. At the same time, I plan to further develop research approaches in which corrosion-resistant materials and protection technologies are designed on the basis of a fundamental understanding of corrosion mechanisms. Through this integration of fundamental corrosion science and practical implementation, my goal is to contribute to the safety and reliability of infrastructure and transportation systems.


