- Address
- 305-0047 1-2-1 Sengen Tsukuba Ibaraki JAPAN [Access]
Research
PublicationsNIMS affiliated publications since 2004.
Research Center for Structural Materials
Elucidation of hydrogen uptake and embrittlement mechanisms using electrochemical methods
Steel, metal, corrosion, hydrogen embrittlement
Overview
In recent years, resource and energy conservation have been promoted to prevent global warming, and in the field of metallic materials, weight reduction of transportation equipment through higher strength is strongly demanded. However, as metallic materials became stronger, they face the problem of an increased susceptibility to hydrogen embrittlement- a fracture phenomenon caused by hydrogen penetrating into the material.
Because hydrogen is the lightest and smallest atom and diffuses easily through metallic materials, its detection is extremely difficult, and many aspects of its behavior within materials remain unclarified. In this study, by utilizing electrochemical techniques and a uniquely developed hydrogen visualization method, we aim to clarify the detailed mechanisms of hydrogen uptake and diffusion behavior. The purpose of this study is to gain insights that contribute to a deeper understanding of the hydrogen embrittlement mechanisms and the establishment of design guidelines for future hydrogen-resistant metallic materials.
Novelty and originality
While conventional electrochemical techniques are excellent for quantitative evaluation, they are limited to macroscopic averages and struggle to capture microscopic, site-specific hydrogen behavior. The originality of this research lies in integrating electrochemical methods with a uniquely developed hydrogen visualization method to achieve both the quantification and visualization of microscopic hydrogen behavior.
Details

To elucidate the hydrogen embrittlement mechanism in metallic materials, it is extremely important to identify the microscopic diffusion pathways through which hydrogen migrates inside the material. However, capturing these local paths has been difficult due to hydrogen's extremely small size and rapid diffusion.
In this study, we broke through this challenge using a newly developed hydrogen visualization method based on metal complexes.
The figure shows an example of visualizing hydrogen preferentially diffusing along nickel grain boundaries. Currently, we are expanding this method to various metallic materials and systematically analyzing how metal microstructure and deformation affect hydrogen diffusion, thereby advancing the elucidation of hydrogen embrittlement mechanisms.
Summary
In this study, we successfully identified microscopic hydrogen diffusion pathways—a task that was previously difficult—by combining electrochemical techniques with a newly developed metal-complex-based hydrogen visualization method. Moving forward, we aim to establish "innovative design guidelines for hydrogen-resistant materials" that contribute to both weight reduction and enhanced safety in transportation equipment by expanding this method to a variety of high-strength metallic materials.


