Solvent-Driven Biphasic
Architectures in Polymer Gels
via Polymerization-Induced Solvent Phase Separation

Yuji Kamiyama; Ryota Tamate; Yuji Kamiyama; Ryota Tamate

doi:10.1021/jacs.6c03722

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Solvent-Driven Biphasic Architectures in Polymer Gels via Polymerization-Induced Solvent Phase Separation

Yuji Kamiyama, Ryota Tamate.

Journal of the American Chemical Society 148 [34] 36414-36422. 2026.

https://doi.org/10.1021/jacs.6c03722

Open Access American Chemical Society (ACS) (Publisher) Materials Data Repository (MDR)

NIMS author(s)

Introduction to new articles

A Solvent-Driven Route to Self-Healing, Shape-Memory, and Crack-Resistant Biphasic Gels

We developed polymerization-induced solvent phase separation (PI-SPS), a one-pot method for creating biphasic gels from two immiscible liquids. These gels exhibit self-healing, shape-memory behavior, and high crack resistance without complex molecular design or additives. Applicable to water, organic solvents, and ionic liquids, the method is expected to enable broad applications across diverse fields.

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Created at: 2026-09-08 03:05:54 +0900 Updated at: 2026-10-09 04:30:52 +0900