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Programmed Assembly of IrAu12 Nanoclusters into Dimers and Trimers: Electron Microscopy Observation and Spectroscopic Characterization

Yuto Fukumoto, Shinjiro Takano, Yosuke Asami, Haru Hirai, Koji Harano, Tatsuya Tsukuda.
Nano Letters 25 [32] 12248-12254. 2025.

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Precision Assembly and Imaging of Metal Nanoclusters Achieved: A New Step Toward Tailored Hierarchical Nanomaterials

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Precise assembly of metal nanoclusters and visualization of their structures at high resolution have been achieved. Various assemblies of IrAu₁₂ nanoclusters—dimers, linear trimers and oligomers, and triangular trimers— were synthesized by reacting pre-programmed Ir–Au nanoclusters with multidentate bridging ligands. A new sample preparation method using polystyrene as a matrix enabled direct visualization of the nanocluster assemblies using scanning transmission electron microscopy.

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Created at: 2025-08-20 03:12:11 +0900 Updated at: 2026-10-03 07:07:23 +0900

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