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Research

Keywords

Ni基単結晶超合金、Ni基鍛造超合金、耐酸化コーティング

PublicationsNIMS affiliated publications since 2004.

Society memberships

日本金属学会, 日本ガスタービン学会

Awards

  • 日本金属学会功績賞 (2019)
  • 平成26年度科学技術分野の文部科学大臣表彰科学技術賞開発部門 (2014)
  • 第13回山崎貞一賞 (2013)
Research Center for Structural Materials
Title

Development of High-Performance Ni-base Superalloys

Keywords

"Ni-base Superalloy", "Creep", "TMF", "Oxidation Resistance"

Overview

Increasing the temperature of combustion gases is essential for improving the efficiency of aircraft jet engines and power-generation gas turbines; consequently, there is a demand for turbine materials capable of withstanding higher operating temperatures. NIMS is developing a wide range of nickel-base single-crystal superalloys for use as turbine blade materials. We conduct material design tailored to specific applications - such as advanced single-crystal superalloys for aircraft engines, low-cost single-crystal superalloys for power-generation gas turbines, and cast-forged or powder-metallurgy superalloys for aircraft engine turbine discs—and perform property evaluations to facilitate the practical implementation of these alloys.

Novelty and originality

Balanced high-temperature strength and oxidation resistance
Balanced high-temperature strength and corrosion resistance
Balanced high-temperature creep properties and thermal fatigue properties

Details

image

The figure on the left plots an index representing oxidation resistance on the vertical axis against creep rupture life at 1100°C/137 MPa on the horizontal axis. While the high-temperature strength of Ni-base single-crystal superalloys has improved with each successive generation, their oxidation resistance has tended to decline. Superalloys from the fifth generation onwards address this by incorporating a greater number of elements that enhance oxidation resistance—while maintaining high-temperature strength—and optimizing the balance between them. TMS-238 is a sixth-generation Ni-base single-crystal superalloy offering excellent high-temperature oxidation and creep strength characteristics; it is expected to see practical application as a high-pressure turbine blade in aircraft engines.
The figure on the right plots thermal fatigue characteristics on the vertical axis against creep rupture life at 1100°C/137 MPa on the horizontal axis. For power generation turbines, the addition of elements such as Re or Ru is considered undesirable due to manufacturing cost considerations. Consequently, TMS-1700—a low-cost Ni-based single-crystal superalloy offering excellent creep strength and thermal fatigue characteristics—was developed with a reduced content of the strengthening element Re. Verification testing is currently underway with a view toward practical application.

Summary

The single-crystal superalloys for turbine blades and the cast-forged/powder-metallurgy superalloys for turbine discs developed by NIMS exhibit superior temperature resistance compared to conventional materials available overseas; their practical application can contribute to reduced fuel consumption and lower CO2 emissions. Efforts are currently underway to bring these alloys into practical use, including the development of recycling technologies and the construction of material property databases; further challenges include process improvements to curb manufacturing costs and the development of repair technologies.

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