Bottom‐Up Assembly of Amorphous Metal–Organic Frameworks From Proton Conductive Metal–Organic Polyhedra

Nattapol Ma; Daiki Umeyama; Hiroki Yamada; Soracha Kosasang; Nattapol Ma; Daiki Umeyama; Hiroki Yamada; Soracha Kosasang

doi:10.1002/smll.73752

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Bottom‐Up Assembly of Amorphous Metal–Organic Frameworks From Proton Conductive Metal–Organic Polyhedra

Nattapol Ma, Daiki Umeyama, Hiroki Yamada, Soracha Kosasang.

Small 22 [36] e73752. 2026.

https://doi.org/10.1002/smll.73752

Open Access Wiley (Publisher) Materials Data Repository (MDR)

NIMS author(s)

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Bottom-Up Assembly of Amorphous MOFs From Proton Conductive Metal-Organic Polyhedra

Structural control in amorphous MOFs (aMOFs) remains challenging compared to their crystalline counterparts. We report a bottom-up strategy using metal-organic polyhedra as predefined building units. By crosslinking these clusters, we preserve intrinsic node functionality within aMOFs, achieving proton conductivity up to 4.8 mS/cm at 85°C and 90% RH.

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Created at: 2026-06-30 03:07:29 +0900 Updated at: 2026-09-02 07:03:00 +0900